Journal
ORGANIC LETTERS
Volume 15, Issue 5, Pages 1044-1047Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4000313
Keywords
-
Categories
Funding
- Platform for Drug Discovery, Informatics, and Structural Life Science from the Ministry of Education, Culture, Sports, Science and Technology, Japan
- MEXT (Ministry of Education, Culture, Sports, Science and Technology) [24105513, 2304]
- JST (ACT-C: Creation of Advanced Catalytic Transformation for the Sustainable Manufacturing at Low Energy, Low Environmental Load)
- Tosoh F-Tech Ltd.
- Hori Sciences & Arts Foundation
- Grants-in-Aid for Scientific Research [24105513] Funding Source: KAKEN
Ask authors/readers for more resources
The regioselective Odifluoromethylation of 1,3-diones was achieved via in situ generation of difluorocarbene from bromodifluoromethylating reagents in the presence of an organic base. A wide variety of difluormethyl enol ethers were obtained in good to excellent yields. The reaction mechanism is discussed based on ab initio calculations (kcal/mol).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available