Journal
ORGANIC LETTERS
Volume 15, Issue 14, Pages 3742-3745Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4016546
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Funding
- Japan Securities Scholarship Foundation and Technology (MEXT), Japan
- JSPS KAKENHI [23655210]
- Grants-in-Aid for Scientific Research [23655210] Funding Source: KAKEN
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An amphiphilic macrocyclic compound consisting of 10 tetra-alkyl phosphonium bromide groups and a pillar[5]arene core was prepared. This compound was soluble in both aqueous and organic media and acted as a highly efficient and substrate-selective phase-transfer catalyst. In particular, oxidation of the linear alkene1-hexene to 1-pentanal by KMnO4 was >99%, whereas that of the branched alkene 4-methyl-1-hexene was only 31%, under ideal conditions.
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