Journal
ORGANIC LETTERS
Volume 15, Issue 12, Pages 3146-3149Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401369d
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Tetrasubstituted pyrroles can be obtained via the reaction of terminal alkynes and Imines using (BuLi)-Bu-n as the base In one step with high chemoselectivity (method 1). Alternatively, the intermediate propargylamines can also react with imines to afford tetrasubstituted pyrroles when using LiHMDS as the base (method 2), which provides a complementary method to construct the pyrroles with different substituents.
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