Journal
ORGANIC LETTERS
Volume 15, Issue 12, Pages 2978-2981Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401128h
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- Research Foundation for Pharmaceutical Sciences
- JSPS Research Fellowship
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [23390003] Funding Source: KAKEN
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An acid-promoted novel cascade cyclization is described. Using 8 equiv of trifluoroacetic acid or a catalytic amount of Lewis acid as the promoter, structurally diverse polycyclic cyclopenta[b]indoles were obtained in moderate to excellent yield. This cascade process was extremely effective for the synthesis of 8-membered ring-fused cyclopenta[b]indole derivatives.
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