Journal
ORGANIC LETTERS
Volume 15, Issue 14, Pages 3678-3681Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401550h
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Funding
- National Natural Science Foundation of China [21172045, 91127041]
- Shanghai Shuguang Program [11SG04]
- Pujiang Program
- Changjiang Scholars and Innovative Research Team in University [IRT1117]
- Shanghai Leading Academic Discipline Project [B108]
- Fudan University
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A robust allylic palladium-NHC complex was developed and exhibited extremely high catalytic activity toward aminocarbonylation of various (hetero)aryl iodides under atmospheric carbon monoxide pressure, in which a broad range of secondary and primary amines were well tolerated. In addition, the concise synthesis of an anticancer drug tamibarotene was accomplished even in a gram scale, further highlighting the practical applicability of the protocol.
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