Journal
ORGANIC LETTERS
Volume 15, Issue 6, Pages 1414-1417Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4004178
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Funding
- NSF [CHE-1111074]
- NIH [GM-47480]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1111074] Funding Source: National Science Foundation
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Two types of NHC-Cu complexes catalyze protoborations of terminal allenes to afford valuable 1,1- or trisubstituted vinylboron species with high site selectivity and stereoselectivity. The scope of the method, application to natural product synthesis, and mechanistic basis for the observed selectivity trends are presented.
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