Journal
ORGANIC LETTERS
Volume 16, Issue 2, Pages 580-583Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4034513
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Funding
- project 973 [2011CB512005]
- Ministry of Education of China [IRT1225]
- National Natural Science Foundation of China [21362002, 41206077, 81260472]
- Guangxi Natural Science Foundation of China [2012GXNSFAA053027, 2011GXNSFD018010]
- Bagui Scholar Program of Guangxi
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A new rare earth metal and samarium-catalyzed C(sp(3))-H bond activation is reported in which 2-alkylazaarenes and propargylic alcohols were converted to indolizines. This process operates under mild conditions and solvent-free conditions. A broad scope of coupling partners has been established, and a likely mechanism has also been suggested.
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