Journal
ORGANIC LETTERS
Volume 16, Issue 1, Pages 286-289Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4032792
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Funding
- MEXT, Japan
- ACT-C from Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [24106742, 24550067] Funding Source: KAKEN
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Two-directional annulation of dibromoisobenzofuran, a formal equivalent to didehydroisobenzofuran, was developed. Importantly, selective bromine lithium exchange allows the tandem generation of benzynes and dual cycloadditions with two different arynophiles. Also described is the application to the synthesis of a substituted pentacene.
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