Journal
ORGANIC LETTERS
Volume 15, Issue 11, Pages 2876-2879Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401208t
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Funding
- National Institutes of Health [GM46059, GM58160]
- Amgen
- National Science Foundation [CHE 9808061, DBI 9729592]
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A series of palladacyclic precatalysts that incorporate electron-rich di-fert-butylphosphino biaryl ligands is reported. These precatalysts are easily prepared, and their use provides a general means of employing bulky ligands in palladium-catalyzed cross-coupling reactions. The application of these palladium sources to various C-N and C-O bond-forming processes is also described.
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