Journal
ORGANIC LETTERS
Volume 15, Issue 16, Pages 4190-4193Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4019002
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Funding
- National Science Foundation [CHE-0848460, 1152488]
- China Scholarship Council [2011635137]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1152488] Funding Source: National Science Foundation
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An efficient catalytic system for the direct intermolecular alpha-arylation of acetamide derivatives with aryl chlorides is presented. Chemoselectivities up to 10:1 in the mono- and diarylation of acetamides were achieved by careful selection of bases, solvents, and stoichiometry. Bis-arylated amides were prepared in up to 95% yield.
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