Journal
ORGANIC LETTERS
Volume 15, Issue 20, Pages 5266-5269Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402492s
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Funding
- National Basic Research Program of China (973 Program) [2012CB821600]
- NSFC [21172242]
- SIOC
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A methyl(phenyl)sulfane-promoted direct olefination of polyfluoroarenes catalyzed by palladium has been reported. With use of this new thioether ligand, a high reaction efficiency and excellent E/Z ratio of desired olefinated polyfluoroarenes were obtained. This represents a first example of thioether promoted oxidative Heck reaction.
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