Journal
ORGANIC LETTERS
Volume 15, Issue 23, Pages 6006-6009Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402895r
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Funding
- MEXT [23685032]
- Ritsumeikan R-GIRO project
- JSPS
- Grants-in-Aid for Scientific Research [24108740, 23685032] Funding Source: KAKEN
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Dimers of appropriately arranged anion-responsive pi-conjugated moieties form helical structures by interaction with chiral anions. Terphenyl-bridged dimers of dipyrrolyldiketone boron complexes show chirality induced by binding L-amino acid anions, as observed by circular dichroism (CD) and circularly polarized luminescence (CPL). The preferred configurations of helical structures depend on the geometries of the terphenyl spacer moieties.
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