Journal
ORGANIC LETTERS
Volume 15, Issue 13, Pages 3230-3233Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4011757
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Funding
- NSFC [20925207, 21072010, 20821062]
- 973 Project from the MOST of China [2009CB825300]
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A variety of important multiarylated benzenes were efficiently synthesized from phloroglucinol derivatives 1 through sequential cross-couplings via Pd-catalyzed C-OTs, Ni-catalyzed C-OC(O)NEt2, and C-OMe bond activation. High selectivity was achieved based on the rational design and inherent diversity in the reactivity of different C-O bonds.
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