Journal
ORGANIC LETTERS
Volume 15, Issue 6, Pages 1378-1381Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4003465
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Funding
- Danish National Research Foundation
- Danish Natural Science Research Council
- Villum Foundation
- Carlsberg Foundation
- Lundbeck Foundation
- Aarhus University
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Aryl iodides and bromides were easily converted to their corresponding aromatic carboxylic acids via a Pd-catalyzed carbonylation reaction using silacarboxylic acids as an in situ source of carbon monoxide. The reaction conditions were compatible with a wide range of functional groups, and with the aryl iodides, the carbonylation was complete within minutes. The method was adapted to the double and selective isotope labeling of tamibarotene.
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