Journal
ORGANIC LETTERS
Volume 15, Issue 20, Pages 5394-5396Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4027655
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Funding
- National Institutes of Health [GM-64444]
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An intramolecular Rh-catalyzed transannulation reaction of alkynyl triazoles has been developed. This method allows efficient construction of various 5,5-fused pyrroles, including tetrahydropyrrolo and Spiro systems. The method demonstrates excellent functional group compatibility. A rhodium carbene-alkyne metathesis mechanism is proposed for this transformation.
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