Journal
ORGANIC LETTERS
Volume 15, Issue 13, Pages 3358-3361Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401407v
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Funding
- National Research Foundation of Korea (NRF)
- Korea government (MSIP) [2011-0018355]
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A rhodium-catalyzed cyclization using alkynes and arylphosphonic acid monoesters for the synthesis of phosphaisocoumarins is reported. A number of arylphosphonic acid monoesters were selectively cyclized in high yields with functional group tolerance. In addition, unsymmetrical alkynes are applied in high regioselectivity.
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