Journal
ORGANIC LETTERS
Volume 16, Issue 2, Pages 358-361Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403142d
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- MEXT-Supported Program for the Strategic Research Foundation at Private Universities
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Isopropyl carbamates derived from benzylamines provide isoindolinones by treatment with phosphorus pentoxide at room temperature. Utility of this Bischler-Napieralski-type cyclization and a new mechanism involving a carbamoyl cation for rationalization of this smooth conversion are discussed.
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