Journal
ORGANIC LETTERS
Volume 15, Issue 5, Pages 1152-1154Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol400055v
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- University of British Columbia
- Natural Science and Engineering Research Council (NSERC) of Canada
- Canada Foundation for Innovation (CFI)
- Canadian Cancer Society Research Institute
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The total synthesis of cladoniamide G, a cytotoxic compound against MCF-7 breast cancer cells (10 mu g/mL), was accomplished. Key steps in the sequence include oxidative dimerization of 3-acetoxy-5-chloroindole and a tandem process incorporating three steps: bimolecular carbonyl addition, lactam formation, and carbamate removal.
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