Journal
ORGANIC LETTERS
Volume 16, Issue 1, Pages 166-169Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403156r
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- Deutsche Forschurigsgemeinschaft [SFB 749]
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The total synthesis of the diterpenoids sandresolide B and amphilectolide from a common furan building block is presented. Key steps include Palladium-mediated carbonylation, lanthanide catalyzed ring closure, Myers alkylation, intramolecular Friedel Crafts acylation, photooxygenation, and a Kornblum-DeLaMare rearrangement.
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