4.8 Article

Synthesis, Properties, and Structures of Functionalized peri-Xanthenoxanthene

Journal

ORGANIC LETTERS
Volume 15, Issue 10, Pages 2382-2385

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol400790d

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Funding

  1. Natural Science Foundation of China [91123034, 21104091]
  2. Knowledge Innovation Programme of the Chinese Academy of Sciences [KJCX2-EW-M02]

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Three types of alkylated peri-xanthenoxanthene (PXX) have been synthesized employing efficient synthetic routes. These heteroaromatic compounds exhibited different electronic and crystal structures according to UV-vis spectra, electrochemical measurements, and X-ray structural analyses. Among them, 1,7-DOPXX has been demonstrated as an active material for organic field-effect transistors with promising mobility and a high on/off ratio simultaneously.

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