Journal
ORGANIC LETTERS
Volume 15, Issue 21, Pages 5582-5585Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4027842
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Funding
- JSPS KAKENHI [23550060]
- Keio Gijuku Academic Development Funds
- Grants-in-Aid for Scientific Research [23550060] Funding Source: KAKEN
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The enantioselective total synthesis of natural enantiomers of clavilactones A and B has been achieved. A key feature of the synthesis is the use of a ring-opening/ring-closing metathesis, which allows the one-pot transformation of a strained cyclobutenecarboxylate into a gamma-butenolide.
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