Journal
ORGANIC LETTERS
Volume 16, Issue 1, Pages 102-105Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403083e
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Funding
- National Basic Research Program of China [2012CB821600, 2012CB215500]
- National Natural Science Foundation of China [21372246, 20825209]
- Chinese Academy of Sciences
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A novel silver(I)-fluoride-mediated homocoupling reaction of beta,beta-difluorostyrene derivatives is described. The transformation is initiated via nucleophilic addition of silver(I) fluoride to beta,beta-difluorostyrenes, which is followed by dimerization of the corresponding benzylsilver intermediates. The reaction shows good substrate scope, functional group tolerance, and represents the first report on the reactivity of (alpha-trifluoromethyl)benzylsilver species.
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