Journal
ORGANIC LETTERS
Volume 16, Issue 1, Pages 208-211Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4032045
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Funding
- Singapore National Research Foundation (NRF Fellowship)
- National University of Singapore
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Quinine-derived urea has been identified as a highly efficient organocatalyst for the enantioselective oxidation of 1,2-diols using bromination reagents as the oxidant. This simple procedure utilizes readily available reagents and operates at ambient temperature to yield a wide range of a-hydroxy ketones in good yield (up to 94%) and excellent enantioselectivity (up to 95% ee).
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