Journal
ORGANIC LETTERS
Volume 15, Issue 18, Pages 4686-4689Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401984j
Keywords
-
Categories
Funding
- MEXT, Japan [24685023, 25102510]
- Grants-in-Aid for Scientific Research [24106710, 24685023, 25102510] Funding Source: KAKEN
Ask authors/readers for more resources
The effect of rotaxane shuttling on the fluorescence properties of a fluorophore was investigated by exploiting fluorophore-tethered [2]rotaxanes. A fluorescent boron enaminoketonate (BEK) moiety was introduced in a rotaxane via transformation of an isoxazole unit generated as a result of an end-capping reaction using a nitrile N-oxide. The rotaxane exhibited a red shift of the fluorescence maximum along with a remarkable enhancement of the fluorescence quantum yield through wheel translation to the fluorophore.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available