Journal
ORGANIC LETTERS
Volume 16, Issue 2, Pages 444-447Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4033336
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Funding
- National Natural Science Foundation of China [21072047, 21172059, 21272059, 21202039, 21372066]
- Excellent Youth Foundation of Henan Scientific Committee [114100510012]
- Program for Innovative Research Team from the University of Henan Province [2012IRTSTHN006]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1061]
- Research Fund for the Doctoral Program of Higher Education of China [2 0124104110006]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [13HASTIT013]
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A highly regioselective Minisci reaction with the decarboxylative alkylation of purine nucleosides under mild conditions was developed. With 5 mol % AgNO3 as a catalyst and (NH4)(2)S2O8 as an oxidant, a series of purine nucleosides including ribosyl, deoxyribosyl, arabinosyl purine nucleosides worked well with primary, secondary, and tertiary aliphatic carboxylic acids.
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