4.8 Article

Porphyrin-Peptoid Conjugates: Face-to-Face Display of Porphyrins on Peptoid Helices

Journal

ORGANIC LETTERS
Volume 15, Issue 7, Pages 1670-1673

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol4004564

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Funding

  1. National Research Foundation of Korea
  2. Korean Government [2011-0014890]
  3. National Research Foundation of Korea [2011-0014890] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Distance, orientation, and number controlled porphyrin-peptoid conjugates (PPCs) were efficiently synthesized. Cofacial (1, 2, and 4), slipped-cofacial (3), and unstructured (5) arrangements of porphyrins provided distinct optical and electronic properties characterized by UV-vis and circular dichroism spectroscopy. In addition, ECCD spectra confirmed the handedness of peptoid helices.

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