Journal
ORGANIC LETTERS
Volume 15, Issue 14, Pages 3790-3793Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401771a
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Funding
- Robert A. Welch Foundation [F-0038]
- NIH-NIGMS [RO1 GM069445]
- Center for Green Chemistry and Catalysis
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Trifluoromethyl substituted allenes engage in ruthenium catalyzed reductive couplings with paraformaldehyde to form products of hydrohydroxymethylation as single regioisomers. This method enables generation of CF3-bearing all-carbon quaternary stereocenters.
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