Journal
ORGANIC LETTERS
Volume 15, Issue 7, Pages 1634-1637Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol400410m
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Funding
- ETH Zurich [ETH 13-11-1]
- Fonds der Chemischen Industrie (Germany)
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A cobalt-catalyzed photochemical synthesis of allylic trifluoromethanes from styrene derivatives using 2,2,2-trifluoroethyl iodide is described. The method complements existing approaches, providing an alternative bond construction strategy to access these compounds. The process may be conducted in continuous mode in a novel photochemical flow reactor, resulting in a notable productivity increase.
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