Journal
ORGANIC LETTERS
Volume 16, Issue 2, Pages 476-479Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4033623
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Funding
- Leverhulme Trust
- EPSRC
- Engineering and Physical Sciences Research Council [1093835] Funding Source: researchfish
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The first asymmetric silylation of unsaturated lactams and amides using Cu(I)-NHC catalysts and PhMe(2)SiBpin has been accomplished. The method has been exploited in an expedient asymmetric synthesis of the (R)-enantiomer of the nootropic drug oxiracetam.
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