Journal
ORGANIC LETTERS
Volume 15, Issue 17, Pages 4548-4551Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402106x
Keywords
-
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG)
Ask authors/readers for more resources
Radical azidooxygenation of various alkenes is described. A readily prepared N-3-iodine(III) reagent acts as a clean N-3-radical precursor. Radical generation is achieved with TEMPONa acting as a mild organic reducing reagent. The C-radical generated after N-3-radical addition is efficiently trapped by in situ generated TEMPO. Yields are good to excellent, and for cyclic systems azidooxygenation occurs with excellent diastereoselectivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available