4.8 Article

Four Levels of Wavelength-Selective Uncaging for Oligonucleotides

Journal

ORGANIC LETTERS
Volume 15, Issue 21, Pages 5500-5503

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol402657j

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Funding

  1. Deutsche Forschungsgemeinschaft [HE 4597/3-1]

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In this study the new nucleobase-caged nucleotides dT(NpHP) and dT(DEACM) are introduced. Together with two other caging groups (NDBF and NPP) this results in four layers of wavelength-selective uncaging for oligonucleotides, sequentially going from 505 to 440 nm, 365 nm, and finally to 313 nm for the photolysis reaction.

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