Journal
ORGANIC LETTERS
Volume 15, Issue 23, Pages 5974-5977Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402843s
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Funding
- National Institutes of Health [R01 GM064357]
- National Science Foundation [CHE 1112370]
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The carbonyl ene reaction of 2-methylenetetrahydropyrans provides a rapid, high yielding route for the preparation of beta-hydroxydihydropyrans under mild conditions. This process provides a new entry for the synthesis of 2-substituted tetrahydropyrans and for the direct introduction of oxygen heterocycles into molecular frameworks.
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