Journal
ORGANIC LETTERS
Volume 15, Issue 20, Pages 5346-5349Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402601j
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- ANR [ANR- 11-BS07-022-01]
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Reaction of bis(2-sulfanylethyl)amido (SEA) peptides with trilsopropylsilylthiol in water at neutral pH yields peptide thiocarboxylates. An alkylthioester derived from beta-alanine was used to trap the released bis(2-sulfanylethyl)amine and displace the equilibrium toward the peptide thiocarboxylate.
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