Journal
ORGANIC LETTERS
Volume 16, Issue 1, Pages 306-309Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403337u
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Funding
- NSF [CHE-0844602]
- NSFC [21228204]
- Direct For Mathematical & Physical Scien [1228336, 0844602] Funding Source: National Science Foundation
- Division Of Chemistry [1228336, 0844602] Funding Source: National Science Foundation
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The gold-catalyzed intermolecular addition of 1,3-dicarbonyl compounds to unactivated 1-alkynes (Nakamura reaction) is achieved at room temperature for the first time through synergistic gold/gallium catalysis. The developed system is highly efficient with a gold catalyst loading that can be as low as 500 ppm.
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