Journal
ORGANIC LETTERS
Volume 15, Issue 17, Pages 4394-4397Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401931s
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Funding
- Universite de Montreal
- Natural Science and Engineering Council of Canada (NSERC)
- Canada Research Chair Program
- Canada Foundation for Innovation
- NSERC
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A Pd-catalyzed, picolinamide-enabled, and efficient C-H arylation of cyclopropanes is described. The reaction can be promoted by either a silver additive or catalytic pivalic acid in the presence of a carbonate base. Various aryl iodides can be employed as coupling partners, providing exclusively cis-substituted cyclopropylpicolinamides.
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