Journal
ORGANIC LETTERS
Volume 15, Issue 6, Pages 1242-1245Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4001697
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- MEXT
- JSPS
- JST, Japan
- Grants-in-Aid for Scientific Research [22550101] Funding Source: KAKEN
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The synthesis of N-vinylcarbazoles was achieved by the palladium-catalyzed aza-Wacker reaction of N-H carbazoles with styrenes. In this reaction, Markovnikov adducts were exclusively produced. In contrast, the reaction with electron-deficient alkenes such as acrylates and acrylamides gave only anti-Markovnikov adducts.
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