Journal
ORGANIC LETTERS
Volume 15, Issue 5, Pages 1088-1091Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol400110c
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- Queen's (6) University Belfast
- Chirotech, Dr. Reddy's Laboratories, Cambridge, UK
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A highly efficient palladium catalyzed decarboxylative allylic rearrangement of alloc indoles has been developed. This can also be combined with a Suzuki-Miyaura cross-coupling reaction in a single pot transformation. Substituted alloc groups and benzylic variants have also been demonstrated alongside promising initial results on the enantioselective variant.
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