Journal
ORGANIC LETTERS
Volume 15, Issue 3, Pages 512-515Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3033237
Keywords
-
Categories
Funding
- National Science Foundation [CHE 0911134]
Ask authors/readers for more resources
Ir(I)-catalyzed enantioselective decarboxylative allylic etherification of aryl allyl carbonates provides aryl allyl ethers. Key to the generality and high stereoselection of the reaction is the use of the intramolecular decarboxylative allylation process and [Ir(dbcot)Cl)(2) as an Ir(I) source. Ir(I)-catalyzed diastereoselective decarboxylative allylic etherification, combined with asymmetric aldehyde crotylation and cross metathesis, can furnish monoprotected 2-methyl-1,3-diols (starting from simple aldehydes) with high diastereoselectivities.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available