Journal
ORGANIC LETTERS
Volume 15, Issue 4, Pages 796-799Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol303469a
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Funding
- National Institutes of General Medical Sciences, National Institutes of Health [GM083944-05]
- Eli Lilly
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This paper describes the catalytic asymmetric diamination of alkyl dienes using N,N-di-tert-butylthiadiaziridine 1,1-dioxide In the presence of Pd(0) and a chiral phosphoramidite ligand to give cyclic sulfamides in high yield and high ee. The diamination is also amenable to gram scale.
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