4.8 Article

Metal-Controlled Cycloaddition of 2-Alkynyl-1,4-benzoquinones and Styrenyl Systems: Lewis Acid versus π Acid

Journal

ORGANIC LETTERS
Volume 15, Issue 10, Pages 2482-2485

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol400956h

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Funding

  1. National Natural Science Foundation of China [21072033, 21102019]

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Metal-controlled cycloaddition of 2-alkynyl-1,4-benzoquinones and electron-rich styrenyl systems were investigated. The density functional theory (OFT) calculations revealed that the regioselectivity of the cycloaddition results from the different activation modes of Bi(OTf)(3) and AuCl.

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