Journal
ORGANIC LETTERS
Volume 15, Issue 13, Pages 3396-3399Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4014365
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Funding
- Pew Scholars Program
- University of California Cancer Research Coordinating Committee funds
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The in vivo and in vitro characterization of AntB, a dedicated acyltransferase encoded in the antimycin biosynthetic gene cluster, which catalyzes the C-8 acyloxy formation is reported. It is demonstrated that AntB has broad substrate specificity toward both the acyl substrate and the acyl carrier and produces more antimycin analogues with varying C-8 acyloxy moieties.
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