4.8 Article

Photochemical Reaction Containers as Energy and Electron-Transfer Agents

Journal

ORGANIC LETTERS
Volume 15, Issue 6, Pages 1326-1329

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol400267k

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Funding

  1. National Science Foundation [NSF-CHE-0848017, NSF-CHE-0946858]
  2. Division Of Chemistry
  3. Direct For Mathematical & Physical Scien [0848017] Funding Source: National Science Foundation

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Two deep cavity cavitands, octa acid and resorcinol-capped octa acid, have been established to be good triplet energy donors in the excited state and electron donors in the ground state to excited acceptors. This property endows them the capacity to be active reaction containers. The above recognition provides opportunities to investigate the excited state chemistry of host-encapsulated guests without the use of secondary triplet energy and electron donors.

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