Journal
ORGANIC LETTERS
Volume 15, Issue 19, Pages 5008-5011Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4023358
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- National Institutes of Health [R01GM063540]
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An efficient protocol for the one-step synthesis of biologically relevant 1,1-diarylalkanes has been described. This reaction introduces two different aryl groups across the terminal end of simple feedstock alkenes such as ethylene and allylic carbonates. The propensity to generate pi-benzylpalladium intermediates dictates the exclusive 1,1-regioselectivity observed in the product.
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