Journal
ORGANIC LETTERS
Volume 14, Issue 24, Pages 6214-6217Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302962p
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Funding
- Chinese Academy of Science
- National Natural Science Foundation [21032006]
- 973 Program of China [2012CBA01200]
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A copper-mediated cross-coupling reaction between HCFC-123 and phenols or thiophenols has been achieved. It is found that diethyl amine, which serves as both the activator and ligand of copper, plays a key role in this reaction. Two possible radical involved processes are proposed for the reaction mechanism.
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