Journal
ORGANIC LETTERS
Volume 14, Issue 2, Pages 624-627Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol203238j
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Funding
- National Science Foundation of China [21072194, 21172222]
- 973 program [2010CB833300]
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This paper describes a Rh(I)-catalyzed highly efficient and enantioselective 1,2-addition of arylboronic acids to alpha-diketones with the use of a simple sulfur-alkene hybrid ligand. With as low as a 0.1 mol % catalyst loading, a variety of optically active alpha-hydroxyketones can be furnished in high yields with excellent ee's.
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