Journal
ORGANIC LETTERS
Volume 14, Issue 21, Pages 5412-5415Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302475g
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- Singapore National Research Foundation (NRF)
- Singapore Economic Development Board (EDB)
- GlaxoSmithKline (GSK)
- Nanyang Technological University (NTU)
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An N-heterocyclic carbene (NHC)-catalyzed annulation reaction of isatin N-Boc ketimines and enals is developed for the synthesis of spirocyclic oxindole-gamma-lactams bearing one quaternary chiral center in good yields and excellent stereoselectivities (up to >20:1 dr and 99% ee).
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