Journal
ORGANIC LETTERS
Volume 14, Issue 3, Pages 866-869Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2033916
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Funding
- MEXT, Japan [23108705]
- Global COE in Chemistry of Nagoya University
- Asahi Glass Foundation
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A biphenyl-fused BODIPY was synthesized through a facile oxidative cyclization of peripheral aryl-substituents at the beta-position of the BODIPY unit. The extended pi-system of the fused BODIPY induces near-infrared (NIR) absorption and strong pi-pi interactions in the solid state. These features are beneficial for the application of the dye as a functional material. The biphenyl-fused BODIPY dye was demonstrated to exhibit photocurrent conversion ability on the basis of its n-type semiconducting property.
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