Journal
ORGANIC LETTERS
Volume 14, Issue 14, Pages 3660-3663Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301503k
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Funding
- University of Erlangen-Nuremberg
- NSERC
- NSERC (PGS-D)
- Alberta Ingenuity Fund
- Alberta Heritage
- Killam Trusts
- National Science Foundation [ECCS-1102275]
- Office of Naval Research
- Div Of Electrical, Commun & Cyber Sys
- Directorate For Engineering [1102275] Funding Source: National Science Foundation
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The synthesis of isomerically pure syn-anthradithiophene derivatives (syn-ADTs) is described. X-ray crystallography is used to compare the solid-state arrangement of syn-ADT derivatives 2a,b to the analogous mixture of syn- and anti-ADTs. Single-crystal OFETs based on isomerically pure syn-ADTs 2a,b display device performance comparable to those based on a mixture of ADT isomers syn/anti-2a,b with mobilities as high as 1 cm(2)/(V s).
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