Journal
ORGANIC LETTERS
Volume 14, Issue 4, Pages 1142-1145Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300075n
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A highly enantioselective chiral Bronsted acid catalyzed propargylation of aldehydes with allenylboronate is described. The reaction is shown to be practical and quite general with a broad substrate scope covering aryl, polyaryl, heteroaryl, alpha,beta-unsaturated, and aliphatic aldehydes.
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