4.8 Article

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3•OEt2

Journal

ORGANIC LETTERS
Volume 14, Issue 17, Pages 4560-4563

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol302024m

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Funding

  1. Nanyang Technological University

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A practical and simple method for deaminoborylation of aryltriazene with bis(pinacolato)diboron has been developed that is mediated by BF3 center dot OEt2. Various arylboronic esters are prepared in moderate to good yields with this facile transition-metal-free procedure.

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